articleTop 1% cited
Oxone as an Inexpensive, Safe, and Environmentally Benign Oxidant for C−H Bond Oxygenation
Organic Letters · 2006 · Vol. 8(6) · pp. 1141–1144
Lopa V. Desai✉(University of Michigan–Ann Arbor)Hasnain A. Malik(University of Michigan–Ann Arbor)Melanie S. Sanford(University of Michigan–Ann Arbor)
Abstract
[reaction: see text] This paper describes the application of peroxide-based oxidants in the Pd(OAc)(2)-catalyzed acetoxylation and etherification of arene and alkane C-H bonds. Oxone in acetic acid and/or methanol proved particularly effective, and these transformations were applied to a wide variety of substrates.
Oxidative Organic Chemistry ReactionsCatalytic C–H Functionalization MethodsSynthesis and Catalytic ReactionsChemistryMethanolAcetic acidAlkaneCatalysisPeroxideCombinatorial chemistryOrganic chemistryOxygenationHydrogen peroxide
MeSH terms
Indicators and ReagentsPeroxidesSulfuric AcidsMolecular StructureOxidantsCombinatorial Chemistry Techniques
Citations
421
FWCI
11.66
field-weighted impact
References
16
Percentile
99%
vs. same field & year
Citations per year
Cited by
Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization
Accounts of Chemical Research · 2012 · 1,350 citations
Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds
Accounts of Chemical Research · 2009 · 1,973 citations
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
Chemical Reviews · 2010 · 6,049 citations
A Simple Catalytic Method for the Regioselective Halogenation of Arenes
Organic Letters · 2006 · 358 citations
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
Chemical Reviews · 2011 · 3,829 citations
Novel Acetoxylation and C−C Coupling Reactions at Unactivated Positions in α-Amino Acid Derivatives
Organic Letters · 2006 · 546 citations
Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp<sup>3</sup>)H Activation
Chemistry - A European Journal · 2010 · 1,074 citations
σ-Chelation-directed C–H functionalizations using Pd(<scp>ii</scp>) and Cu(<scp>ii</scp>) catalysts: regioselectivity, stereoselectivity and catalytic turnover
Organic & Biomolecular Chemistry · 2006 · 303 citations
Citation Network
How this paper connects to the literature. Drag to explore, click any node to open that paper.
