articleTop 10% cited
A Simple Catalytic Method for the Regioselective Halogenation of Arenes
Organic Letters · 2006 · Vol. 8(12) · pp. 2523–2526
Dipannita Kalyani✉(University of Michigan–Ann Arbor)Allison R. Dick(University of Michigan–Ann Arbor)Waseem Q. Anani(University of Michigan–Ann Arbor)Melanie S. Sanford(University of Michigan–Ann Arbor)
Abstract
This paper describes a mild palladium-catalyzed method for the regioselective chlorination, bromination, and iodination of arene C-H bonds using N-halosuccinimides as oxidants. These transformations have been applied to a wide array of substrates and can provide products that are complementary to those obtained via conventional electrophilic aromatic substitution reactions. [reaction: see text]
Vanadium and Halogenation ChemistryCatalytic C–H Functionalization MethodsOxidative Organic Chemistry ReactionsHalogenationRegioselectivityChemistryElectrophileCatalysisElectrophilic aromatic substitutionPalladiumCombinatorial chemistryElectrophilic substitutionOrganic chemistry
MeSH terms
CatalysisHydrocarbons, HalogenatedPalladiumPolycyclic Aromatic HydrocarbonsStereoisomerismMolecular Structure
Citations
358
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8.97
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References
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Organic Letters · 2006 · 421 citations
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
Angewandte Chemie International Edition · 2003 · 2,521 citations
Copper in cross-coupling reactions
Coordination Chemistry Reviews · 2004 · 1,536 citations
Electrophilic aromatic substitution
Journal of Organometallic Chemistry · 1990 · 342 citations
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
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