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Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
Chemistry - A European Journal · 2010 · Vol. 16(37) · pp. 11212–11222
Tetsuya Satoh✉(Osaka University)Masahiro Miura✉(Osaka University)
Abstract
Aromatic substrates with oxygen- and nitrogen-containing substituents undergo oxidative coupling with alkynes and alkenes under rhodium catalysis through regioselective C-H bond cleavage. Coordination of the substituents to the rhodium center is the key to activate the C-H bonds effectively. Various fused-ring systems can be constructed through these reactions.
Catalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsCyclopropane Reaction MechanismsRhodiumRegioselectivityChemistryCatalysisOxidative coupling of methaneBond cleavageRing (chemistry)Oxidative phosphorylationCleavage (geology)Organic chemistry
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References
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