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Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage
Synthesis · 2008 · Vol. 2008(19) · pp. 3013–3039
Abstract
Catalytic functionalization of unreactive C-H bond has become one of the most attractive research subjects in modern organic chemistry. To date, a variety of catalytic reactions involving C-H bond cleavage have been reported. In this review, we briefly survey the reported research with respect to efficient and selective transition-metal-catalyzed C-C bond formation via C-H bond cleavage.
Catalytic C–H Functionalization MethodsAsymmetric Hydrogenation and CatalysisCatalytic Cross-Coupling ReactionsChemistryCatalysisBond cleavageTransition metalCarbon–hydrogen bond activationCleavage (geology)Carbon fibersReinforced carbon–carbonOrganic chemistryPhotochemistry
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