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Local composition model for excess Gibbs energy of electrolyte systems. Part I: Single solvent, single completely dissociated electrolyte systems

AIChE Journal · 1982 · Vol. 28(4) · pp. 588–596

Chau‐Chyun Chen✉(Massachusetts Institute of Technology)H.I. Britt(Massachusetts Institute of Technology)Joseph Boston(Massachusetts Institute of Technology)Lawrence B. Evans(Massachusetts Institute of Technology)

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Abstract

Abstract An electrolyte local composition model is developed for excess Gibbs energy, which is assumed to be the sum of two contributions, one resulting from long range electrostatic forces between ions and the other from short range forces between all the species. The validity of the model is demonstrated for systems emcompassing the entire range from molecular liquid to fused salt.

Chemical and Physical Properties in Aqueous Solutions Thermodynamic properties of mixtures Ionic liquids properties and applicationsElectrolyteGibbs free energyRange (aeronautics)Composition (language)ChemistrySolventThermodynamicsSalt (chemistry)IonMaterials science

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