articleTop 10% cited
Thermodynamic properties of strong electrolytes in aqueous solutions
AIChE Journal · 1973 · Vol. 19(2) · pp. 313–320
Abstract
Abstract A generalized analytic correlation is presented for activity coefficient. osmotic coefficient, enthalpy, and heat capacity of single and multicomponent strong aqueous solutions. A good correlation for each salt to an ionic strength of six is obtained by assigning a single parameter “ B ” value to each salt. These B values are well approximated by assigning two parameters for each ion. Values presented for the common ions at 25°C allow the estimation of activity and osmotic coefficients of many unmeasured salt solutions.
Chemical and Physical Properties in Aqueous SolutionsThermodynamic properties of mixturesSpectroscopy and Quantum Chemical StudiesOsmotic coefficientAqueous solutionActivity coefficientThermodynamicsSalt (chemistry)ElectrolyteEnthalpyChemistryIonIonic bonding
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References
The physical chemistry of electrolytic solutions
Journal of the Franklin Institute · 1950 · 3,038 citations
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