articleTop 10% cited
A local composition model for the excess Gibbs energy of aqueous electrolyte systems
AIChE Journal · 1986 · Vol. 32(3) · pp. 444–454
Chau‐Chyun Chen✉(AspenTech (United States))Lawrence B. Evans(Massachusetts Institute of Technology)
Abstract
Abstract The electrolyte nonrandom two‐liquid (NRTL) model proposed by Chen et al. (1982) is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.
Chemical and Physical Properties in Aqueous SolutionsThermodynamic properties of mixturesSpectroscopy and Quantum Chemical StudiesElectrolyteNon-random two-liquid modelThermodynamicsGibbs free energyAqueous solutionActivity coefficientChemistryBinary numberBinary systemPhysical chemistry
Citations
890
FWCI
5.79
field-weighted impact
References
23
Percentile
97%
vs. same field & year
Citations per year
Cited by
Carbon capture and storage update
Energy & Environmental Science · 2013 · 2,278 citations
Carbon capture and storage (CCS): the way forward
Energy & Environmental Science · 2018 · 4,009 citations
References
Thermodynamic properties of strong electrolytes in aqueous solutions
AIChE Journal · 1973 · 901 citations
Thermodynamics of electrolytes. I. Theoretical basis and general equations
The Journal of Physical Chemistry · 1973 · 3,369 citations
Local composition model for excess Gibbs energy of electrolyte systems. Part I: Single solvent, single completely dissociated electrolyte systems
AIChE Journal · 1982 · 871 citations
Local compositions in thermodynamic excess functions for liquid mixtures
AIChE Journal · 1968 · 6,621 citations
Chemical engineers' handbook
Journal of the Franklin Institute · 1950 · 2,722 citations
Citation Network
How this paper connects to the literature. Drag to explore, click any node to open that paper.