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Formation of Aryl−Nitrogen, Aryl−Oxygen, and Aryl−Carbon Bonds Using Well-Defined Copper(I)-Based Catalysts
Organic Letters · 2001 · Vol. 3(26) · pp. 4315–4317
Rattan K. Gujadhur✉(University of Massachusetts Amherst)Craig G. Bates(University of Massachusetts Amherst)D. Venkataraman(University of Massachusetts Amherst)
Abstract
We report mild synthetic protocols for the formation of aryl-carbon, aryl-nitrogen, and aryl-oxygen bonds based on soluble, well-defined copper(I) catalysts. These protocols do not require the use of palladium and/or expensive ligands. [structure: see text]
Catalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsCyclopropane Reaction MechanismsArylChemistryCatalysisCopperNitrogenPalladiumCarbon fibersOxygenOrganic chemistryCombinatorial chemistry
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Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C−N Bond Formation with a Commercial Ligand
The Journal of Organic Chemistry · 1999 · 764 citations
An efficient copper-catalyzed coupling of aryl halides with imidazoles
Tetrahedron Letters · 1999 · 346 citations
Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation
Accounts of Chemical Research · 1998 · 1,763 citations
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