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A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines
Angewandte Chemie International Edition in English · 1995 · Vol. 34(12) · pp. 1348–1350
Anil S. Guram✉(Massachusetts Institute of Technology)Roger A. Rennels✉(Massachusetts Institute of Technology)Stephen L. Buchwald✉(Massachusetts Institute of Technology)
Abstract
A facile Pd-catalyzed method for the preparation of a wide variety of aryl amines from aryl bromides and amines has been developed [Eq. (a)]. Noteworthy features of this method include the experimental simplicity, the tin/boron-free conditions, and the broad spectrum of potential substrates.
Catalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsChemical Synthesis and ReactionsArylCatalysisCombinatorial chemistryTinSimplicityChemistryBoronBroad spectrumSimple (philosophy)Organic chemistry
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References
Tetrahedron report number 163
Tetrahedron · 1984 · 2,240 citations
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