articleTop 1% cited
Biarylphosphanliganden in der palladiumkatalysierten Aminierung
Angewandte Chemie · 2008 · Vol. 120(34) · pp. 6438–6461
D. Surry✉(Massachusetts Institute of Technology)Stephen L. Buchwald(Massachusetts Institute of Technology)
Abstract
Abstract In den vergangenen 12 Jahren erfuhr die palladiumkatalysierte Aminierung von Arylhalogeniden eine rasche Entwicklung, die durch die Einführung neuer Ligandenklassen vorangetrieben wurde. Biarylphosphane liefern in diesem Zusammenhang besonders reaktive Katalysatoren. Dieser Aufsatz behandelt Anwendungen solcher Katalysatoren zur C‐N‐Kreuzkupplung in der Synthese von Heterocyclen und Pharmazeutika, in den Materialwissenschaften und in der Naturstoffsynthese.
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