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Metal‐Free Oxidative Carbon‐Heteroatom Bond Formation Through C–H Bond Functionalization
European Journal of Organic Chemistry · 2013 · Vol. 2013(26) · pp. 5769–5804
Rajarshi Samanta✉(Max Planck Institute of Molecular Physiology)Kiran Matcha(Max Planck Institute of Molecular Physiology)Andrey P. Antonchick(Max Planck Institute of Molecular Physiology)
Abstract
Abstract Direct methods of carbon‐heteroatom bond formation through functionalization of non‐reactive C–H bonds represent an attractive approach to the synthesis of interesting products. This review focuses on the development of metal‐free coupling methods for unactivated compounds under oxidative reaction conditions. The utility of these methods in syntheses of desired products and the mechanisms of their formation are discussed with numerous examples.
Catalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsSynthesis and Catalytic ReactionsChemistrySurface modificationHeteroatomOxidative coupling of methaneCombinatorial chemistryCoupling reactionOrganic chemistryRing (chemistry)Catalysis
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References
Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation
Organic Letters · 2011 · 590 citations
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
Angewandte Chemie · 2009 · 1,165 citations
Facile Oxidation of Aldehydes to Acids and Esters with Oxone
Organic Letters · 2003 · 458 citations
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