articleTop 1% cited
Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation
Organic Letters · 2011 · Vol. 13(15) · pp. 3852–3855
Durga Prasad Hari✉(University of Regensburg)Burkhard König(University of Regensburg)
Abstract
Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.
Catalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesEosin YChemistryMalononitrileVisible spectrumCatalysisOxidative phosphorylationEosinPhotochemistryOxidative coupling of methaneTetrahydroisoquinoline
Funding
- Deutsche Forschungsgemeinschaft
Citations
590
FWCI
31.52
field-weighted impact
References
54
Percentile
100%
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Citations per year
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References
Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence
Coordination Chemistry Reviews · 1988 · 4,790 citations
Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations
Accounts of Chemical Research · 2008 · 2,745 citations
Visible light photoredox catalysis: applications in organic synthesis
Chemical Society Reviews · 2010 · 4,059 citations
Visible Light-Mediated Intermolecular C−H Functionalization of Electron-Rich Heterocycles with Malonates
Organic Letters · 2010 · 355 citations
Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues
Coordination Chemistry Reviews · 1982 · 1,898 citations
Visible light photocatalysis as a greener approach to photochemical synthesis
Nature Chemistry · 2010 · 2,609 citations
Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
Chemical Reviews · 2011 · 3,829 citations
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