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Rhodium-Catalyzed Conjugate Addition of Aryl- or 1-Alkenylboronic Acids to Enones

Organometallics · 1997 · Vol. 16(20) · pp. 4229–4231

Masaaki Sakai✉(Hokkaido University)Hiroyuki Hayashi(Hokkaido University)Norio Miyaura(Hokkaido University)

Abstract

The rhodium(I)-catalyzed conjugate addition of aryl- or 1-alkenylboronic acids to enones was carried out in high yields at 50 °C in an aqueous solvent. A combination of (acac)Rh(CO)2 and dppb was recognized to be highly effective for the addition to acyclic and cyclic enones.

Catalytic Cross-Coupling Reactions Catalytic C–H Functionalization Methods Organoboron and organosilicon chemistryChemistryRhodiumConjugateArylCatalysisSolventAqueous solutionMedicinal chemistryAqueous mediumAddition reaction

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