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How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr<sub>3</sub> Cells

The Journal of Physical Chemistry Letters · 2015 · Vol. 6(13) · pp. 2452–2456
Michael KulbakDavid CahenGary Hodes

Abstract

Hybrid organic-inorganic lead halide perovskite photovoltaic cells have already surpassed 20% conversion efficiency in the few years that they have been seriously studied. However, many fundamental questions still remain unanswered as to why they are so good. One of these is "Is the organic cation really necessary to obtain high quality cells?" In this study, we show that an all-inorganic version of the lead bromide perovskite material works equally well as the organic one, in particular generating the high open circuit voltages that are an important feature of these cells.

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchSolid-state spectroscopy and crystallographyPerovskite (structure)HalidePhotovoltaic systemLead (geology)Materials scienceEnergy conversion efficiencyOptoelectronicsInorganic chemistryChemistryElectrical engineering

Funding

  • Leona M. and Harry B. Helmsley Charitable Trust
Citations
1,078
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How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr<sub>3</sub> Cells · Scinovex