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Entropic stabilization of mixed A-cation ABX<sub>3</sub> metal halide perovskites for high performance perovskite solar cells

Energy & Environmental Science · 2015 · Vol. 9(2) · pp. 656–662
Chenyi YiJingshan LuoSimone MeloniAriadni BozikiNegar Ashari AstaniCarole GrätzelShaik M. ZakeeruddinUrsula RöthlisbergerMichaël Grätzel

Abstract

A mixture of CsPbI<sub>3</sub> and FAPbI<sub>3</sub> is thermodynamically stabilized in the perovskite phase with respect to the pure δ phases.

Perovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyQuantum Dots Synthesis And PropertiesPerovskite (structure)HalideMaterials scienceMetalChemical engineeringInorganic chemistryABX testChemistryMetallurgy

Funding

  • National Science Foundation
  • European Commission
  • École Polytechnique Fédérale de Lausanne
  • Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
  • Partnership for Advanced Computing in Europe AISBL
  • King Abdulaziz City for Science and Technology
  • Centro Svizzero di Calcolo Scientifico
  • National Supercomputing Centre Singapore
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