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Green oxidation with aqueous hydrogen peroxide
Chemical Communications · 2003 · pp. 1977–1977
Ryōji Noyori✉(Nagoya University)Masayo Aoki(Tokyo Institute of Technology)Kazuhiko Sato(National Institute of Advanced Industrial Science and Technology)
Abstract
Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in an economically, technically, and environmentally satisfying manner.
Chemical Synthesis and ReactionsVanadium and Halogenation ChemistryMicrowave-Assisted Synthesis and ApplicationsTungstateHydrogen peroxideAqueous solutionHalideCatalysisChemistryAmmoniumSolventPhase-transfer catalystSodium tungstate
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References
Hydrogen peroxide oxidation catalyzed by heteropoly acids combined with cetylpyridinium chloride. Epoxidation of olefins and allylic alcohols, ketonization of alcohols and diols, and oxidative cleavage of 1,2-diols and olefins
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