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Facile Synthesis of α‐ and β‐<i>O</i>‐Glycosyl Imidates; Preparation of Glycosides and Disaccharides
Angewandte Chemie International Edition in English · 1980 · Vol. 19(9) · pp. 731–732
Richard R. Schmidt(University of Konstanz)Josef Michel✉(University of Konstanz)
Abstract
Simplification of glycoside and saccharide syntheses is possible with the aid of the readily isolable β- and α-glycosyl imidates (1) and (2). These key compounds are conveniently prepared from C-1-unprotected glucopyranose. Compounds of type (2) were formerly unknown.
Carbohydrate Chemistry and SynthesisEnzyme Production and CharacterizationEnzyme Catalysis and ImmobilizationGlycosylGlycosideChemistryGlycosyl donorStereochemistryOrganic chemistryCombinatorial chemistry
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