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Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework

Chemistry of Materials · 2009 · Vol. 21(8) · pp. 1410–1412
Janosch CravillonSimon MünzerSven‐Jare LohmeierArmin FeldhoffKlaus HuberMichael Wiebcke

Abstract

Simply reacting Zn(NO3)2·6H2O with an excess of 2-methylimidazole in methanol at room temperature yields well-shaped nanocrystals of ZIF-8 with a narrow size distribution. The rapid growth has been monitored by time-resolved static light scattering. Nanoscale ZIF-8 powder is microporous and thermally stable up to ca. 200 °C.

Metal-Organic Frameworks: Synthesis and ApplicationsMagnesium Oxide Properties and ApplicationsAdvanced ceramic materials synthesisMicroporous materialZeolitic imidazolate frameworkNanocrystalImidazolateMaterials scienceNanoscopic scaleCharacterization (materials science)Chemical engineeringMethanolNanotechnology
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References
Nanozeolites:  Synthesis, Crystallization Mechanism, and Applications
Chemistry of Materials · 2005 · 1,135 citations
Zeolite membranes – Recent developments and progress
Microporous and Mesoporous Materials · 2008 · 721 citations
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Proceedings of the National Academy of Sciences · 2006 · 7,256 citations
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