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Synthetically Tailored Excited States: Phosphorescent, Cyclometalated Iridium(III) Complexes and Their Applications
Chemistry - A European Journal · 2006 · Vol. 12(31) · pp. 7970–7977
Michael S. Lowry✉(Princeton University)Stefan Bernhard(Princeton University)
Abstract
Phosphorescent iridium(III) complexes are being widely explored for their utility in diverse photophysical applications. The performance of these materials in such roles depends heavily on their excited-state properties, which can be tuned through ligand and substituent effects. This concept article focuses on methods for synthetically tailoring the properties of bis-cyclometalated iridium(III) materials, and explores the factors governing the nature of their lowest excited state.
Organic Light-Emitting Diodes ResearchLanthanide and Transition Metal ComplexesLuminescence and Fluorescent MaterialsIridiumPhosphorescenceExcited stateSubstituentLigand (biochemistry)Materials sciencePhotochemistryNanotechnologyChemistryOrganic chemistry
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Synthetic Control of Excited-State Properties in Cyclometalated Ir(III) Complexes Using Ancillary Ligands
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