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Tailorable and programmable liquid-crystalline elastomers using a two-stage thiol–acrylate reaction

RSC Advances · 2015 · Vol. 5(25) · pp. 18997–19001
Christopher M. YakackiMohand O. SaedDevatha P. NairTao GongScott M. ReedChristopher N. Bowman

Abstract

A methodology is introduced to synthesize main-chain liquid-crystalline elastomers (LCEs) using a thiol–acrylate-based reaction. This method can program an aligned LCE monodomain and offer spatio-temporal control over liquid-crystalline behavior.

Advanced Materials and MechanicsPolymer composites and self-healingAdvanced Sensor and Energy Harvesting MaterialsAcrylateElastomerLiquid crystallineMaterials scienceThiolPolymer chemistryChemical engineeringComposite materialOrganic chemistryPolymer

Funding

  • National Science Foundation
  • University of Colorado Denver
  • Division of Civil, Mechanical and Manufacturing Innovation
Citations
533
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18.97
field-weighted impact
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40
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100%
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Cited by
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References
Review of progress in shape-memory polymers
Journal of Materials Chemistry · 2007 · 1,902 citations
Thiol–Ene Click Chemistry
Angewandte Chemie International Edition · 2010 · 4,026 citations
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Tailorable and programmable liquid-crystalline elastomers using a two-stage thiol–acrylate reaction · Scinovex