articleTop 1% cited
Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents
Organic Letters · 2008 · Vol. 10(11) · pp. 2299–2302
Lutz Ackermann✉(University of Göttingen)R. Vicente(University of Göttingen)Andreas Althammer(University of Göttingen)
Abstract
Catalytic amounts of aromatic carboxylic acid MesCO H enabled efficient ruthenium-catalyzed direct arylations in apolar solvents with unparalleled broad scope via a concerted deprotonation-metalation mechanism.
Catalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsAsymmetric Hydrogenation and CatalysisRutheniumChemistryDeprotonationCatalysisMetalationCarboxylic acidOrganic chemistryCombinatorial chemistryIon
Funding
- Deutsche Forschungsgemeinschaft
Citations
391
FWCI
17.97
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References
Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides
The Journal of Organic Chemistry · 2002 · 8,416 citations
Phosphine Oxides as Preligands in Ruthenium-Catalyzed Arylations via C−H Bond Functionalization Using Aryl Chlorides
Organic Letters · 2005 · 369 citations
A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes
Angewandte Chemie International Edition · 2002 · 11,380 citations
1.3‐Dipolare Cycloadditionen Rückschau und Ausblick
Angewandte Chemie · 1963 · 1,296 citations
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