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Guest-induced gate-opening of a zeolite imidazolate framework

New Journal of Chemistry · 2010 · Vol. 35(3) · pp. 546–550
Sónia AguadoG. BergeretMarc Pera TitusVirginie MoizanCarlos Nieto‐DraghiNicolas BatsDavid Farrusseng

Abstract

The zinc benzimidazolate coordination polymer (ZIF-7) shows a reversible gate-opening effect upon variation of partial pressure of CO2 or temperature. This phenomenon, which is unique for a MOF with sodalite topology, arises from a phase-to-phase transformation upon guest adsorption–desorption.

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and ApplicationsChemistrySodaliteImidazolateDesorptionZeolitic imidazolate frameworkPhase (matter)ZeoliteTopology (electrical circuits)AdsorptionTransformation (genetics)

Funding

  • Agence Nationale de la Recherche
  • CHIST-ERA
Citations
186
FWCI
6.43
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References
26
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97%
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Cited by
Current Status of Metal–Organic Framework Membranes for Gas Separations: Promises and Challenges
Industrial & Engineering Chemistry Research · 2011 · 493 citations
References
Functional Micropore Chemistry of Crystalline Metal Complex-Assembled Compounds
Bulletin of the Chemical Society of Japan · 1998 · 834 citations
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Proceedings of the National Academy of Sciences · 2006 · 7,256 citations
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