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General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy

Applied Physics Letters · 2006 · Vol. 88(16)
Luiz Gustavo CançadoKazuyuki TakaiToshiaki EnokiMorinobu EndoYoong Ahm KimHiroshi MizusakiAdo JórioL. N. CoelhoR. Magalhães‐PaniagoM. A. Pimenta

Abstract

This work presents a systematic study of the ratio between the integrated intensities of the disorder-induced D and G Raman bands (ID∕IG) in nanographite samples with different crystallite sizes (La) and using different excitation laser energies. The crystallite size La of the nanographite samples was obtained both by x-ray diffraction using synchrotron radiation and directly from scanning tunneling microscopy images. A general equation for the determination of La using any laser energy in the visible range is obtained. Moreover, it is shown that ID∕IG is inversely proportional to the fourth power of the laser energy used in the experiment.

Graphene research and applicationsCarbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchCrystalliteRaman spectroscopyLaserMaterials scienceDiffractionSpectroscopySynchrotron radiationAnalytical Chemistry (journal)Range (aeronautics)Optics
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References
Raman Spectrum of Graphite
The Journal of Chemical Physics · 1970 · 10,463 citations
Characterization of diamond films by Raman spectroscopy
Journal of materials research/Pratt's guide to venture capital sources · 1989 · 2,479 citations
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