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Thiol-Capping of CdTe Nanocrystals:  An Alternative to Organometallic Synthetic Routes

The Journal of Physical Chemistry B · 2002 · Vol. 106(29) · pp. 7177–7185
Nikolai GaponikDmitri V. TalapinAndrey L. RogachKathrin HoppeElena V. ShevchenkoAndreas KornowskiAlexander EychmüllerHorst Weller

Abstract

New approaches to synthesize photostable thiol-capped CdTe nanocrystals are reported. Post-preparative size-selective precipitation and selective photochemical etching have been developed as methods providing an increase of photoluminescence quantum efficiency of the nanocrystals of up to 40%. Some advantages of thiol-capping in comparison to conventional organometallic syntheses of quantum dots are discussed.

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and ApplicationsNanocrystalCadmium telluride photovoltaicsQuantum dotThiolNanotechnologyMaterials sciencePhotoluminescenceEtching (microfabrication)ChemistryOptoelectronics
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