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Reduction of natural enones in the presence of cerium trichloride
Journal of the Chemical Society Chemical Communications · 1978 · Vol. 0(14) · pp. 601–602
Abstract
The reduction of αβ-unsaturated ketones with sodium borohydride in methanol solution in the presence of cerium chloride gives almost exclusively the allylic alcohol, sometimes stereoselectively; the reduction of a variety of natural products containing a conjugated keto-group is described.
Advanced Synthetic Organic ChemistryAsymmetric Synthesis and CatalysisSynthetic Organic Chemistry MethodsSodium borohydrideChemistryConjugated systemCeriumMethanolAlcoholAllylic rearrangementReduction (mathematics)Organic chemistryMedicinal chemistry
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