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Chiral Monophosphines as Ligands for Asymmetric Organometallic Catalysis.
Chemical and Pharmaceutical Bulletin · 2000 · Vol. 48(3) · pp. 315–324
Franz Lagasse✉Henri B. Kagan(Institut de Chimie Moléculaire et des Matériaux d'Orsay)
Abstract
Chelating chiral diphosphines are often used as ligands of organometallic complexes. However monophosphines, or more generally ligands with one phosphorus linked to one or several heteroatom, may also be useful. This review gives the main results obtained in that area, by considering the classes of monodentate chiral ligands bearing one P(III) atom and involved in asymmetric catalysis with organometallic complexes.
Inorganic and Organometallic ChemistryAsymmetric Hydrogenation and CatalysisHistory and advancements in chemistryDiphosphinesChemistryDenticityOrganometallic chemistryHeteroatomEnantioselective synthesisGroup 2 organometallic chemistryChelationCatalysisStereochemistry
MeSH terms
CatalysisLigandsOrganometallic CompoundsPhosphinesStereoisomerism
Citations
189
FWCI
14.89
field-weighted impact
References
4
Percentile
100%
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Citations per year
References
Asymmetric catalysis in organic synthesis
European Journal of Medicinal Chemistry · 1994 · 1,968 citations
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Chiral Monophosphines as Ligands for Asymmetric Organometallic Catalysis.
Chemical and Pharmaceutical Bulletin · 2000 · 189 citations
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