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1-Alkyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts: a novel family of electrophilic fluorinating agents

Journal of the Chemical Society Chemical Communications · 1992 · pp. 595–595

R. E. BANKS✉Suad N. Mohialdin-KhaffafG. S. LALIqbal SharifRobert G. Syvret

Abstract

Members of a new series of solid, easily handled, storable, transportable, commercially viable, site-selective electrophilic fluorinating agents of the +N–F class (tradenamed Selectfluor reagents) have been synthesized via direct fluorination of monoquaternary salts of 1,4-diazabicyclo[2.2.2]octane.

Fluorine in Organic Chemistry Inorganic Fluorides and Related Compounds Synthesis and Reactions of Organic CompoundsSelectfluorOctaneElectrophileChemistryReagentElectrophilic fluorinationDABCOAlkylCombinatorial chemistryOrganic chemistry

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247

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12.09

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