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D

Dieter Seebàch

ORCID https://orcid.org/0000-0002-2861-4130

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Top Publications

Methods of Reactivity Umpolung

Angewandte Chemie International Edition in English19791,228 citationsFirst authorCorresponding

Structure and Reactivity of Lithium Enolates. From Pinacolone to Selective <i>C</i>‐Alkylations of Peptides. Difficulties and Opportunities Afforded by Complex Structures

Angewandte Chemie International Edition in English1988812 citationsFirst authorCorresponding

β-Peptides: a surprise at every turn

Chemical Communications1997771 citationsFirst authorCorresponding

β‐Peptides: Synthesis by <i>Arndt‐Eistert</i> homologation with concomitant peptide coupling. Structure determination by NMR and CD spectroscopy and by X‐ray crystallography. Helical secondary structure of a β‐hexapeptide in solution and its stability towards pepsin

Helvetica Chimica Acta1996717 citationsFirst authorCorresponding

Umpolung of the Reactivity of Carbonyl Compounds Through Sulfur-Containing Reagents

Synthesis1977697 citations

Generation and synthetic applications of 2-lithio-1,3-dithianes

The Journal of Organic Chemistry1975567 citationsFirst authorCorresponding

Methoden der Reaktivitätsumpolung

Angewandte Chemie1979543 citationsFirst authorCorresponding

Synthesis of Open‐Chain 2,3‐Disubstituted 4‐nitroketones by Diastereoselective <i>Michael</i>‐addition of (<i>E</i>)‐Enamines to (<i>E</i>)‐Nitroolefins. A topological rule for C, C‐bond forming processes between prochiral centres. Preliminary communication

Helvetica Chimica Acta1981376 citationsFirst authorCorresponding

<sup>13</sup>C‐NMR.‐Spektroskopie von Organolithiumverbindungen bei tiefen Temperaturen. Strukturinformation aus der <sup>13</sup>C, <sup>6</sup>Li‐Kopplung

Helvetica Chimica Acta1983372 citationsFirst authorCorresponding

Nucleophile Acylierung mit 2-Lithium-1,3-dithianen bzw. -1,3,5-trithianen<sup>1,2,3</sup>

Synthesis2003370 citationsFirst authorCorresponding

Probing the Helical Secondary Structure of Short‐Chain β‐Peptides

Helvetica Chimica Acta1996319 citationsFirst authorCorresponding

Substitution of HMPT by the cyclic urea DMPU as a cosolvent for highly reactive nucleophiles and bases

Helvetica Chimica Acta1982311 citations

β<sup>2</sup>‐ and β<sup>3</sup>‐Peptides with Proteinaceous Side Chains: Synthesis and solution structures of constitutional isomers, a novel helical secondary structure and the influence of solvation and hydrophobic interactions on folding

Helvetica Chimica Acta1998303 citationsFirst authorCorresponding

Chirale Alkoxytitan(IV)‐Komplexe für enantioselektive nucleophile Additionen an Aldehyde und als <i>Lewis</i>‐Säuren in <i>Diels‐Alder</i>‐Reaktionen

Helvetica Chimica Acta1987297 citationsFirst authorCorresponding

Herstellung von Hilfsstoffen für die asymmetrische Synthese aus Weinsäure. Addition von Butyllithium an Aldehyde in chiralem Medium

Helvetica Chimica Acta1977271 citationsFirst authorCorresponding

Preparation of Achiral and of Enantiopure Geminally Disubstituted β-Amino Acids for β-Peptide Synthesis

European Journal of Organic Chemistry2000264 citations

On the Mechanisms of Enantioselective Reactions Using α,α,α′,α′ ‐Tetraaryl‐1,3‐dioxolane‐4,5‐dimethanol(TADDOL)‐Derived Titanates: Differences between <i>C</i><sub>2</sub>‐ and <i>C</i><sub>1</sub>‐symmetrical TADDOLs – facts, implications and generalizations

Helvetica Chimica Acta1992227 citationsFirst authorCorresponding

Are Oxazolidinones Really Unproductive, Parasitic Species in Proline Catalysis? – Thoughts and Experiments Pointing to an Alternative View

Helvetica Chimica Acta2007225 citationsFirst authorCorresponding

γ‐Peptides Forming More Stable Secondary Structures than α‐Peptides: Synthesis and helical NMR‐solution structure of the γ‐hexapeptide analog of H‐(Val‐Ala‐Leu)<sub>2</sub>‐OH

Helvetica Chimica Acta1998216 citationsCorresponding

Dieter Seebàch · Scinovex