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Thermodynamic assessment of FE-SI liquid alloys at 900k via the Chou model
International Journal of Physics and Applications · 2025 · Vol. 7(2) · pp. 199–204
Roma Kumari✉(Tilka Manjhi Bhagalpur University)Nirjar Vrind(Tilka Manjhi Bhagalpur University)Jagdhar Mandal(Tilka Manjhi Bhagalpur University)Indu Shekhar Jha(Tilka Manjhi Bhagalpur University)Krishna Kumar(Tilka Manjhi Bhagalpur University)Mritunjay Kumar(Tilka Manjhi Bhagalpur University)
Abstract
The thermodynamic behavior of Fe-Si liquid alloys is of considerable interest for understanding steelmaking processes and the role of silicon as a deoxidizer. In this study, the Chou model of solution thermodynamics is applied to evaluate the excess Gibbs free energy of mixing, activity, enthalpy of mixing and entropy of Fe-Si binary liquid alloys at 900 K. The model predictions are compared with available experimental and CALPHAD data, showing satisfactory agreement. The results provide a reliable basis for understanding alloying effects in Fe-Si melts.
Metallurgical Processes and ThermodynamicsSolidification and crystal growth phenomenaMetallurgical and Alloy ProcessesCALPHADGibbs free energyEntropy of mixingEnthalpyEntropy (arrow of time)Mixing (physics)Enthalpy of mixingActivity coefficientWork (physics)
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