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Thermodynamic assessment of FE-SI liquid alloys at 900k via the Chou model

International Journal of Physics and Applications · 2025 · Vol. 7(2) · pp. 199–204
Roma KumariNirjar VrindJagdhar MandalIndu Shekhar JhaKrishna KumarMritunjay Kumar

Abstract

The thermodynamic behavior of Fe-Si liquid alloys is of considerable interest for understanding steelmaking processes and the role of silicon as a deoxidizer. In this study, the Chou model of solution thermodynamics is applied to evaluate the excess Gibbs free energy of mixing, activity, enthalpy of mixing and entropy of Fe-Si binary liquid alloys at 900 K. The model predictions are compared with available experimental and CALPHAD data, showing satisfactory agreement. The results provide a reliable basis for understanding alloying effects in Fe-Si melts.

Metallurgical Processes and ThermodynamicsSolidification and crystal growth phenomenaMetallurgical and Alloy ProcessesCALPHADGibbs free energyEntropy of mixingEnthalpyEntropy (arrow of time)Mixing (physics)Enthalpy of mixingActivity coefficientWork (physics)
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