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Selected Synthetic Strategies to Spirocyclics
Synthesis · 2009 · Vol. 2009(02) · pp. 165–193
Abstract
The design and synthesis of spirocycles is a challenging task because it involves the creation of a quaternary center, which itself is considered to be one of the most difficult tasks among synthetic transformations. Some recent approaches based on metathesis, cycloaddition and transition-metal-mediated transformations to spirocycles are described here.
Synthetic Organic Chemistry MethodsCyclopropane Reaction MechanismsAsymmetric Hydrogenation and CatalysisChemistryTask (project management)CycloadditionCombinatorial chemistryOlefin metathesisMetathesisOrganic chemistrySystems engineeringEngineering
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