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A ZnCl<sub>2</sub> water-in-salt electrolyte for a reversible Zn metal anode

Chemical Communications · 2018 · Vol. 54(100) · pp. 14097–14099
Chong ZhangJohn HoloubekXianyong WuAigerim DaniyarLiangdong ZhuCheng ChenDaniel P. LeonardIsmael A. Rodríguez‐PérezJia‐Xing JiangChong FangXiulei Ji

Abstract

We report a low-cost water-in-salt electrolyte, of 30 m ZnCl2, which enables a dendrite-free Zn metal anode to possess a high coulombic efficiency (CE). In asymmetric Zn‖Zn cells with a limited mass of plated Zn as the working electrode, the ZnCl2 WiSE improves the average CE of the Zn anode to 95.4% from 73.2% in 5 m ZnCl2.

Advanced battery technologies researchAdvanced Battery Materials and TechnologiesSupercapacitor Materials and FabricationAnodeElectrolyteSalt (chemistry)MetalZincInorganic chemistryChemistryZinc compoundsMaterials scienceElectrode

Funding

  • National Science Foundation
  • Oregon State University
  • National Natural Science Foundation of China
  • China Scholarship Council
Citations
713
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26.61
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