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Co-Doped CuO Nanoarray: An Efficient Oxygen Evolution Reaction Electrocatalyst with Enhanced Activity

ACS Sustainable Chemistry & Engineering · 2018 · Vol. 6(3) · pp. 2883–2887
Xiaoli XiongChaoqun YouZhiang LiuAbdullah M. AsiriXuping Sun

Abstract

It is highly desired to enhance the catalytic activity of oxygen evolution reaction (OER) electrocatalysts made of earth-abundant elements. In this Letter, we report that the OER activity of a CuO nanoarray can be largely enhanced by Co doping. In 1.0 M KOH, the Co-CuO nanoarray on copper foam requires a current densities of 50 and 100 mA cm–2 at overpotentials of only 299 and 330 mV, respectively. It also shows superior long-term durability over 15 h with a turnover frequency of 0.056 mol O2 s–1 at an overpotential of 300 mV.

Electrocatalysts for Energy ConversionAdvanced battery technologies researchCopper-based nanomaterials and applicationsOverpotentialOxygen evolutionElectrocatalystCatalysisChemical engineeringDopingMaterials scienceOxygenCopperNanotechnology

Funding

  • National Natural Science Foundation of China
Citations
324
FWCI
12.87
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