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Transition of lithium growth mechanisms in liquid electrolytes

Energy & Environmental Science · 2016 · Vol. 9(10) · pp. 3221–3229
Peng BaiJu LiFikile R. BrushettMartin Z. Bazant

Abstract

Root-growing, containable mossy lithium changes to tip-growing, short-causing dendritic lithium at “Sand's capacity”, which is set by electrolyte diffusion limitation.

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced Battery Technologies ResearchElectrolyteLithium (medication)ChemistryTransition (genetics)Materials scienceChemical engineeringInorganic chemistryBiochemistryPhysical chemistryInternal medicine

Funding

  • National Science Foundation
  • U.S. Department of Energy
  • Robert Bosch
  • Division of Materials Research
  • Basic Energy Sciences
Citations
1,523
FWCI
48.84
field-weighted impact
References
64
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100%
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Citations per year
References
Lithium metal anodes for rechargeable batteries
Energy & Environmental Science · 2013 · 4,565 citations
Diffusion-Limited Aggregation, a Kinetic Critical Phenomenon
Physical Review Letters · 1981 · 5,317 citations
Dendrite short-circuit and fuse effect on Li/polymer/Li cells
Electrochimica Acta · 2006 · 574 citations
Dendritic growth mechanisms in lithium/polymer cells
Journal of Power Sources · 1999 · 919 citations
High rate and stable cycling of lithium metal anode
Nature Communications · 2015 · 2,463 citations
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