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NMR reveals the surface functionalisation of Ti<sub>3</sub>C<sub>2</sub>MXene

Physical Chemistry Chemical Physics · 2016 · Vol. 18(7) · pp. 5099–5102
Michael A. HopeAlexander C. ForseKent J. GriffithMaria R. LukatskayaMichael GhidiuYury GogotsiClare P. Grey

Abstract

(1)H and (19)F NMR experiments have identified and quantified the internal surface terminations of Ti3C2Tx MXene. -F and -OH terminations are shown to be intimately mixed and there are found to be significantly fewer -OH terminations than -F and -O, with the proportions highly dependent on the synthesis method.

MXene and MAX Phase Materials2D Materials and ApplicationsFerroelectric and Negative Capacitance DevicesSurface (topology)Materials scienceCrystallographyChemistryChemical engineeringStereochemistryGeometryMathematicsEngineering

Funding

  • Engineering and Physical Sciences Research Council
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NMR reveals the surface functionalisation of Ti<sub>3</sub>C<sub>2</sub>MXene · Scinovex