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Earth-abundant hydrogen evolution electrocatalysts

Chemical Science · 2013 · Vol. 5(3) · pp. 865–878
James R. McKoneSmaranda C. MarinescuBruce S. BrunschwigJay R. WinklerHarry B. Gray

Abstract

Splitting water to hydrogen and oxygen is a promising approach for storing energy from intermittent renewables, such as solar power. Efficient, scalable solar-driven electrolysis devices require active electrocatalysts made from earth-abundant elements. In this mini-review, we discuss recent investigations of homogeneous and heterogeneous hydrogen evolution electrocatalysts, with emphasis on our own work on cobalt and iron complexes and nickel-molybdenum alloys.

Electrocatalysts for Energy ConversionAdvanced battery technologies researchMetalloenzymes and iron-sulfur proteinsOxygen evolutionWater splittingRenewable energyElectrolysis of waterHydrogenEarth (classical element)MolybdenumHydrogen productionElectrolysisNickel

Funding

  • National Science Foundation
  • U.S. Department of Energy
  • Office of Science
  • Division of Chemistry
Citations
718
FWCI
24.87
field-weighted impact
References
150
Percentile
100%
vs. same field & year
Citations per year
References
Solar Water Splitting Cells
Chemical Reviews · 2010 · 9,183 citations
Powering the planet: Chemical challenges in solar energy utilization
Proceedings of the National Academy of Sciences · 2006 · 8,164 citations
Artificial photosynthesis for solar water-splitting
Nature Photonics · 2012 · 2,034 citations
Trends in the Exchange Current for Hydrogen Evolution
Journal of The Electrochemical Society · 2005 · 5,664 citations
A review on non-precious metal electrocatalysts for PEM fuel cells
Energy & Environmental Science · 2011 · 1,811 citations
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