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Dual Catalysis Sees the Light: Combining Photoredox with Organo‐, Acid, and Transition‐Metal Catalysis

Chemistry - A European Journal · 2014 · Vol. 20(14) · pp. 3874–3886
Matthew N. HopkinsonBasudev SahooJun‐Long LiFrank Glorius

Abstract

The photoredox activation of organic substrates with visible light is a powerful methodology that generates reactive radical species under very mild conditions. When combined with another catalytic process in a dual catalytic system, novel, visible-light-promoted transformations have been realized that do not proceed using either catalyst in isolation. In this minireview, the state of the art in organic reactions mediated by dual catalytic systems merging photoredox activation with organo-, acid or metal catalysis is discussed.

Radical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsCatalysisPhotoredox catalysisVisible spectrumPhotochemistryChemistryTransition metalDual roleDual (grammatical number)Organic synthesisCombinatorial chemistry
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References
Visible light photoredox catalysis: applications in organic synthesis
Chemical Society Reviews · 2010 · 4,059 citations
When Organocatalysis Meets Transition‐Metal Catalysis
European Journal of Organic Chemistry · 2010 · 606 citations
Photoredoxkatalyse mit sichtbarem Licht
Angewandte Chemie · 2012 · 541 citations
Visible‐Light Photoredox Catalysis
Angewandte Chemie International Edition · 2012 · 2,216 citations
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