article
The phenyldimethylsilyl group as a masked form of the hydroxy group
Journal of the Chemical Society Chemical Communications · 1984 · pp. 29–29
Abstract
The phenyldimethylsilyl group can be converted in two steps, protodesilylation and peracid-mediated rearrangement, into a hydroxy group with retention of configuration: β-phenyldimethylsilyl carbonyl compounds are thus revealed to be masked aldol products.
Synthetic Organic Chemistry MethodsAsymmetric Synthesis and CatalysisChemical Synthesis and ReactionsGroup (periodic table)Aldol reactionChemistryStereochemistryProtecting groupCarbonyl groupOrganic chemistryCatalysis
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