article
Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh<sub>3</sub>)<sub>2</sub>]
Journal of the Chemical Society Chemical Communications · 1982 · pp. 811–813
Abstract
The first metallabenzene,[O[graphic omitted]H)(CO)(PPh3)2] has been prepared from [Os(Co)(CS)(PPh3)3] and ethyen; X- ray crystal structure determination reveals a planar six-membered ring with no significant alternation of C–C bond lengths thus supporting the idea of electron delocalization within the ring.
Organometallic Complex Synthesis and CatalysisCoordination Chemistry and OrganometallicsAsymmetric Hydrogenation and CatalysisDelocalized electronAlternation (linguistics)Ring (chemistry)CrystallographyElectron delocalizationChemistryCrystal structurePlanarCrystal (programming language)Bond length
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