articleTop 1% cited
A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
Chemical Communications · 2006 · pp. 2563–2565
So‐Hye Cho(Northwestern University)Bao‐Qing Ma(Northwestern University)SonBinh T. Nguyen✉(Northwestern University)Joseph T. Hupp✉(Northwestern University)Thomas E. Albrecht‐Schmitt(Auburn University)
Abstract
A new microporous metal-organic framework compound featuring chiral (salen)Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.
Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsMagnetism in coordination complexesOlefin fiberMicroporous materialCatalysisEnantioselective synthesisSelectivityEnantiomerSubstrate (aquarium)Metal-organic frameworkManganeseChemistry
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