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In situ high pressure study of ZIF-8 by FTIR spectroscopy

Chemical Communications · 2011 · Vol. 47(47) · pp. 12694–12694

Yue Hu(Western University)Hossein Kazemian(Western University)Sohrab Rohani(Western University)Yining Huang✉(Western University)Yang Song✉(Western University)

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Abstract

ZIF-8 as a promising storage material was investigated at high pressures up to ~39 GPa by in situ FTIR spectroscopy for the first time. Structural modifications are found to be reversible in a low-pressure region but irreversible in a high-pressure region. Overall, the ZIF-8 framework exhibits an unusual chemical stability even under extreme compression.

Metal-Organic Frameworks: Synthesis and Applications Boron and Carbon Nanomaterials Research Organic and Molecular Conductors ResearchFourier transform infrared spectroscopyHigh pressureIn situSpectroscopyMaterials scienceCompression (physics)Chemical engineeringChemistryThermodynamicsComposite material

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