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Fast Lithium Ion Conduction in Garnet‐Type Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub>

Angewandte Chemie International Edition · 2007 · Vol. 46(41) · pp. 7778–7781
Ramaswamy MuruganVenkataraman ThangaduraiW. Weppner

Abstract

Low activation energy and fast lithium ion conduction have been observed for the new compound Li7La3Zr2O12. Relative to previously reported lithium garnets, the solid electrolyte shows a larger cubic lattice constant, higher lithium ion concentration, lower degree of chemical interaction between the Li+ ions and the other lattice constituents, and higher densification.

Advanced Battery Materials and TechnologiesCrystal Structures and PropertiesSolid-state spectroscopy and crystallographyIonLithium (medication)Fast ion conductorElectrolyteLattice constantLattice (music)Thermal conductionMaterials scienceActivation energyAnalytical Chemistry (journal)
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