articleTop 1% cited
Synthesis and catalytic properties of MIL-100(Fe), an iron(<scp>iii</scp>) carboxylate with large pores
Chemical Communications · 2007 · pp. 2820–2822
Patricia Horcajada(Centre National de la Recherche Scientifique)Suzy Surblé(Centre National de la Recherche Scientifique)Christian Serre✉(Centre National de la Recherche Scientifique)Do‐Young Hong(Korea Research Institute of Chemical Technology)You‐Kyong Seo(Korea Research Institute of Chemical Technology)Jong‐San Chang(Korea Research Institute of Chemical Technology)Jean−Marc Grenèche(Centre National de la Recherche Scientifique)I. Margiolaki(European Science Foundation)Gérard Férey(Université de Versailles Saint-Quentin-en-Yvelines)
Abstract
The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe).
Metal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and CharacterizationCovalent Organic Framework ApplicationsCarboxylateCatalysisHydrothermal circulationChemistrySelectivitySynchrotronPowder diffractionHydrothermal reactionHydrothermal synthesisChemical engineering
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References
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