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Synthesis and catalytic properties of MIL-100(Fe), an iron(<scp>iii</scp>) carboxylate with large pores

Chemical Communications · 2007 · pp. 2820–2822
Patricia HorcajadaSuzy SurbléChristian SerreDo‐Young HongYou‐Kyong SeoJong‐San ChangJean−Marc GrenècheI. MargiolakiGérard Férey

Abstract

The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe).

Metal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and CharacterizationCovalent Organic Framework ApplicationsCarboxylateCatalysisHydrothermal circulationChemistrySelectivitySynchrotronPowder diffractionHydrothermal reactionHydrothermal synthesisChemical engineering
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References
Metal–organic frameworks—prospective industrial applications
Journal of Materials Chemistry · 2005 · 2,276 citations
Crystallized Frameworks with Giant Pores:  Are There Limits to the Possible?
Accounts of Chemical Research · 2005 · 1,317 citations
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