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The Preparation of Merrifield‐Resins Through Total Esterification With Cesium Salts

Helvetica Chimica Acta · 1973 · Vol. 56(5) · pp. 1476–1482
B. F. Gisin

Abstract

Abstract The reaction of chloromethylated polystyrene‐ co ‐1%‐divinylbenzene resin with the cesium salts of N‐protected amino acids proceeds fast and without side reactions to give N‐protected amino acyl resin esters free of quaternary ammonium sites or reactive chloride.

Chemical Synthesis and AnalysisChemical Synthesis and ReactionsAsymmetric Synthesis and CatalysisChemistryCaesiumDivinylbenzeneAmmoniumPolystyreneOrganic chemistrySalt (chemistry)ChlorideAmmonium chlorideIon-exchange resin
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References
<b>Solid Phase Peptide Synthesis. I. The Synthesis of a Tetrapeptide</b>
Journal of the American Chemical Society · 1963 · 7,509 citations
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