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Tellurium substitution effect on superconductivity of the α-phase iron selenide

Europhysics Letters (EPL) · 2008 · Vol. 84(3) · pp. 37002–37002
K. C. YehTzu-Wen HuangYi‐Lin HuangTa-Kun ChenFong-Chi HsuPhillip M. WuYong-Chi LeeYan-Yi ChuChi‐Liang ChenJiu-Yong LuoDer-Chung YanMaw‐Kuen Wu

Abstract

We have carried out a systematic study of the PbO-type compound FeSe_{1-x}Te_x (x = 0~1), where Te substitution effect on superconductivity is investigated. It is found that superconducting transition temperature reaches a maximum of Tc=15.2K at about 50% Te substitution. The pressure-enhanced Tc of FeSe0.5Te0.5 is more than 10 times larger than that of FeSe. Interestingly, FeTe is no longer superconducting. A low temperature structural distortion changes FeTe from triclinic symmetry to orthorhombic symmetry. We believe that this structural change breaks the magnetic symmetry and suppresses superconductivity in FeTe.

Iron-based superconductors researchRare-earth and actinide compoundsSelenideSubstitution (logic)SuperconductivityTelluriumPhase (matter)ChemistryMaterials scienceCondensed matter physicsSeleniumInorganic chemistry
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