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Polymerization of <i>N</i>‐vinylcarbazole by gaseous initiators
Journal of Applied Polymer Science · 1992 · Vol. 44(1) · pp. 173–175
Suraj N. Bhadani✉(Ranchi University)Sumanta K. Sen Gupta(Ranchi University)Arvind Kumar Sinha(Ranchi University)
Abstract
Abstract The polymerization of N ‐vinylcarbazole initiated with NO 2 and SO 2 in dichloroethane has been studied. The kinetics of polymerization were followed gravimetrically. The Polymerization is fast with NO 2 but a relatively slow rate was obtained with SO 2 . The polymerization with these gases appears to be initiated by a charge transfer mechanism.
Synthesis and properties of polymersMolecular Junctions and NanostructuresSilicone and Siloxane ChemistryPolymerizationChain-growth polymerizationIonic polymerizationKineticsPolymer chemistryCationic polymerizationChemistryChain transferDichloroethaneMaterials science
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