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Carbocycles from donor–acceptor cyclopropanes

Organic & Biomolecular Chemistry · 2014 · Vol. 13(3) · pp. 655–671

Huck K. Grover(Transnational Press London)Michael R. Emmett(Western University)Michael A. Kerr✉(Transnational Press London)

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Abstract

This review summarizes research directed towards the formation of carbocyclic adducts from donor-acceptor cyclopropanes. The focus of the review is on annulation and cycloaddition reactions (both inter- and intramolecularly) mediated by Lewis or protic acid, bases, or thermal conditions. Rearrangements resulting in carbocycles and those reactions mediated by transition metal catalysis have been excluded.

Cyclopropane Reaction Mechanisms Catalytic Alkyne Reactions Asymmetric Synthesis and CatalysisAnnulationChemistryCycloadditionAdductLewis acids and basesCatalysisAcceptorMedicinal chemistryStereochemistryOrganic chemistry

Funding

Natural Sciences and Engineering Research Council of Canada

Citations

502

FWCI

23.67

field-weighted impact

References

Percentile

100%

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Citations per year

References

Recent advances in donor–acceptor (DA) cyclopropanes

Tetrahedron · 2004 · 687 citations

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