articleTop 10% cited
Monomeric, volatile bivalent amides of group IV<sub>B</sub>elements, M(NR<sup>1</sup><sub>2</sub>)<sub>2</sub>and M(NR<sup>1</sup>R<sup>2</sup>)<sub>2</sub>(MGe, Sn, or Pb; R<sup>1</sup>Me<sub>3</sub>Si, R<sup>2</sup>Me<sub>3</sub>C)
Journal of the Chemical Society Chemical Communications · 1974 · pp. 895–896
Abstract
The reactions of SnCl2, PbCl2, or GeCl2, dioxan with LiNR12, OEt2 or LiNR1R2, OEt2 in Et2O at 0° yield the stable, monomeric, diamagnetic, coloured, volatile, hydrocarbon-soluble title compounds which are highly reactive.
Chemical Synthesis and ReactionsInorganic and Organometallic ChemistrySynthesis and characterization of novel inorganic/organometallic compoundsChemistryMonomerYield (engineering)DiamagnetismHydrocarbonGroup 2 organometallic chemistryRadiochemistryStereochemistryInorganic chemistryMolecule
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