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A new route to substituted 3-methoxycarbonyldihydropyrans; enantioselective synthesis of (–)-methyl elenolate

Abstract

A stereoselective chiral synthesis of (–)-methyl elenolate has been achieved by employing a newly developed method for the construction of substituted 3-methoxycarbonyldihydropyrans based on a radical cyclisation reaction.

Radical Photochemical ReactionsAxial and Atropisomeric Chirality SynthesisMarine Toxins and Detection MethodsEnantioselective synthesisStereoselectivityChemistryCombinatorial chemistryStereochemistryOrganic chemistryCatalysis
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