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Solvent–solute interactions in ionic liquids

Physical Chemistry Chemical Physics · 2003 · Vol. 5(13) · pp. 2790–2794
Lorna CrowhurstPhilip R. MawdsleyJuan M. Perez‐ArlandisPaul A. SalterTom Welton

Abstract

A range of ionic liquids has been investigated using the Kamlet–Taft parameters α, β, and π*. It was found that π* is high for all of the ionic liquids studied and varies with both anion and cation, α is generally moderate and depends mainly on the cation, β is also moderate and depends mainly on the anion. Comparison is made with other polarity measurements in ionic liquids.

Ionic liquids properties and applicationsThermodynamic properties of mixturesChemical and Physical Properties in Aqueous SolutionsIonic liquidIonSolventPolarity (international relations)ChemistryIonic bondingSolvent polarityChemical physicsInorganic chemistryPhysical chemistry
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