articleTop 1% cited
Solvent–solute interactions in ionic liquids
Physical Chemistry Chemical Physics · 2003 · Vol. 5(13) · pp. 2790–2794
Lorna Crowhurst(Imperial College London)Philip R. Mawdsley(Imperial College London)Juan M. Perez‐Arlandis(Imperial College London)Paul A. Salter(Imperial College London)Tom Welton✉(Imperial College London)
Abstract
A range of ionic liquids has been investigated using the Kamlet–Taft parameters α, β, and π*. It was found that π* is high for all of the ionic liquids studied and varies with both anion and cation, α is generally moderate and depends mainly on the cation, β is also moderate and depends mainly on the anion. Comparison is made with other polarity measurements in ionic liquids.
Ionic liquids properties and applicationsThermodynamic properties of mixturesChemical and Physical Properties in Aqueous SolutionsIonic liquidIonSolventPolarity (international relations)ChemistryIonic bondingSolvent polarityChemical physicsInorganic chemistryPhysical chemistry
Citations
765
FWCI
16.79
field-weighted impact
References
37
Percentile
100%
vs. same field & year
Citations per year
Cited by
Ionic liquids synthesis and applications: An overview
Journal of Molecular Liquids · 2019 · 1,169 citations
Ionic Liquids and Deep Eutectic Solvents in Natural Products Research: Mixtures of Solids as Extraction Solvents
Journal of Natural Products · 2013 · 460 citations
Physicochemical Properties and Structures of Room Temperature Ionic Liquids. 2. Variation of Alkyl Chain Length in Imidazolium Cation
The Journal of Physical Chemistry B · 2005 · 1,656 citations
Dissolution of lignocellulosic materials and its constituents using ionic liquids—A review
Industrial Crops and Products · 2010 · 567 citations
Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions
Green Chemistry · 2007 · 761 citations
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
Chemical Reviews · 2011 · 12,533 citations
Ionic liquids in catalysis
Coordination Chemistry Reviews · 2004 · 1,579 citations
Ionic liquids and catalysis: Recent progress from knowledge to applications
Applied Catalysis A General · 2009 · 1,619 citations
References
Molecular states of water in room temperature ionic liquidsElectronic Supplementary Information available. See http://www.rsc.org/suppdata/cp/b1/b106900d/
Physical Chemistry Chemical Physics · 2001 · 1,415 citations
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
Chemical Reviews · 2011 · 12,533 citations
Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, .pi.*, .alpha., and .beta., and some methods for simplifying the generalized solvatochromic equation
The Journal of Organic Chemistry · 1983 · 3,538 citations
Ionic Liquids—New “Solutions” for Transition Metal Catalysis
Angewandte Chemie International Edition · 2000 · 5,692 citations
Solvatochromic Dyes as Solvent Polarity Indicators
Chemical Reviews · 1994 · 5,383 citations
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
Chemical Reviews · 1999 · 11,714 citations
Citation Network
How this paper connects to the literature. Drag to explore, click any node to open that paper.
