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Definition of the halogen bond (IUPAC Recommendations 2013)

Pure and Applied Chemistry · 2013 · Vol. 85(8) · pp. 1711–1713

Gautam R. Desiraju✉(Indian Institute of Science Bangalore)P Shing Ho(Colorado State University)Lars Kloo(KTH Royal Institute of Technology)A. C. Legon(University of Bristol)Roberto Marquardt(Université de Strasbourg)Pierangelo Metrangolo(Politecnico di Milano)Peter Politzer(Cleveland Medical Devices)Giuseppe Resnati(Politecnico di Milano)Kari Rissanen(University of Jyväskylä)

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Abstract

This recommendation proposes a definition for the term “halogen bond”, which designates a specific subset of the inter- and intramolecular interactions involving a halogen atom in a molecular entity.

Chemical Thermodynamics and Molecular Structure History and advancements in chemistry Crystallography and molecular interactionsChemistryChemical nomenclatureHalogenHalogen bondComputational chemistryOrganic chemistryAlkyl

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